Ruthenium complexes of sterically-hindered pentaarylcyclopentadienyl ligands

被引：3

作者：

Asato, Ryosuke ^{[1
,2
]}

Martin, Colin J. ^{[2
]}

Gisbert, Yohan ^{[3
]}

Abid, Seifallah ^{[3
]}

Kawai, Tsuyoshi ^{[1
,2
]}

Kammerer, Claire ^{[3
]}

Rapenne, Gwenael ^{[1
,2
,3
]}

机构：

[1] NAIST, Nara Inst Sci & Technol, Div Mat Sci, 8916-5 Takayama Cho, Nara 6300192, Japan

[2] CNRS, UPR 8011, NAIST, Int Collaborat Lab Supraphotoact Syst,CEMES, 29 Rue Marvig, F-31055 Toulouse 4, France

[3] Univ Toulouse, CNRS, CEMES, 29 Rue Marvig, F-31055 Toulouse 4, France

来源：

RSC ADVANCES | 2021年 / 11卷 / 33期

基金：

欧盟地平线“2020”;

关键词：

DYNAMIC KINETIC RESOLUTION; MOLECULAR MOTORS; RACEMIZATION; DERIVATIVES; SWITCHES; ALCOHOLS; SANDWICH; METHYL; BULKY;

D O I：

10.1039/d1ra03875c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of ruthenium complexes incorporating an overcrowded pentaarylcyclopentadienyl ligand has been investigated, and higher efficiency has been reached using chlorine-functionalised precursors when compared with their brominated counterparts. A new methodology for the preparation of chlorocyclopentadienes has been developed which is well adapted for highly sterically hindered compounds and works with either electron rich or poor systems.

引用

页码：20207 / 20215

页数：9

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