Nucleophilic catalysis of nitrosation: relationship between nitrosating agent equilibrium constant and catalyst nucleophilicity

被引：15

作者：

da Silva, G ^{[1
]}

Kennedy, EM ^{[1
]}

Dlugogorski, BZ ^{[1
]}

机构：

[1] Univ Newcastle, Sch Engn, Proc Safety & Environm Protect Res Grp, Callaghan, NSW 2308, Australia

来源：

JOURNAL OF CHEMICAL RESEARCH-S | 2002年 / 12期

关键词：

nitrosation; nucleophilic catalysis; thermodynamic nucleophilicity;

D O I：

10.3184/030823402103171069

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Equilibrium constants for the formation of nitrosating agents from various nucleophiles and nitrous acid are predicted from Edwards' nucleophilic parameter.

引用

页码：589 / 590

页数：2

共 14 条

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