Surface Modification of Sulfur Electrodes by Chemically Anchored Cross-Linked Polymer Coating for Lithium-Sulfur Batteries

被引：41

作者：

Lim, Sanghyun ^{[1
]}

Thankamony, Roshni Lilly ^{[1
]}

Yim, Taeeun ^{[2
]}

Chu, Hodong ^{[1
]}

Kim, Young-Jun ^{[2
]}

Mun, Junyoung ^{[3
]}

Kim, Tae-Hyun ^{[1
]}

机构：

[1] Incheon Natl Univ, Dept Chem, Organ Mat Synth Lab, Inchon 406772, South Korea

[2] Korea Elect Technol Inst, Adv Batteries Res Ctr, Songnam 463816, Gyeonggi Do, South Korea

[3] Incheon Natl Univ, Dept Energy & Chem Engn, Inchon 406772, South Korea

来源：

ACS APPLIED MATERIALS & INTERFACES | 2015年 / 7卷 / 03期

关键词：

lithium-sulfur batteries; polymer coating; chemical bonding; Cu anchoring; sulfur electrode; polysulfide dissolution; COMPOSITE CATHODES; POROUS CARBON; PERFORMANCE; POLYSULFIDE;

D O I：

10.1021/am508528p

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Lithium-sulfur batteries suffer from severe self-discharge due to polysulfide dissolution into electrolytes. In this work, a chemically anchored polymer-coated (CAPC) sulfur electrode was prepared, through chemical bonding by coordinated Cu ions and cross-linking, to improve cyclability for Li/S batteries. This electrode retained specific capacities greater than 665 mAh g(-1) at high current density of 3.35 A g(-1) (2C rate) after 100 cycles with an excellent Coulombic efficiency of 100%.

引用

页码：1401 / 1405

页数：5

共 50 条

[1] Pitaya-Like Sulfur Electrodes by Chemically Anchored Polyaniline Shell for Lithium-Sulfur Batteries
Wang, Yan
Wang, Wenxuan
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2017, 12 (12): : 11929 - 11941
[2] Multifunctional cross-linked polymer-Laponite nanocomposite binder for lithium-sulfur batteries
Guo, Rongnan
Wang, Jianli
Zhang, Shunlong
Han, Wei-Qiang
CHEMICAL ENGINEERING JOURNAL, 2020, 388 (388)
[3] Reversible cross-linked phosphorylate binder for recyclable lithium-sulfur batteries
Wang, Hui
Zhang, Guangzhao
Chen, Yukun
Zheng, Peitao
Yi, Huan
Deng, Yonghong
Yang, Yu
Wang, Chaoyang
CHEMICAL ENGINEERING JOURNAL, 2023, 452
[4] Surface Modification of Sulfur Cathodes with PEDOT:PSS Conducting Polymer in Lithium-Sulfur Batteries
Lee, Jeongyeon
Choi, Wonchang
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2015, 162 (06) : A935 - A939
[5] Linear and Cross-Linked Ionic Liquid Polymers as Binders in Lithium-Sulfur Batteries
Vizintin, Alen
Guterman, Ryan
Schmidt, Johannes
Antonietti, Markus
Dominko, Robert
CHEMISTRY OF MATERIALS, 2018, 30 (15) : 5444 - 5450
[6] In-situ polymerized cross-linked binder for cathode in lithium-sulfur batteries
Heng Ye
Danni Lei
Lu Shen
Bin Ni
Baohua Li
Feiyu Kang
Yan-Bing He
ChineseChemicalLetters, 2020, 31 (02) : 570 - 574
[7] In-situ polymerized cross-linked binder for cathode in lithium-sulfur batteries
Ye, Heng
Lei, Danni
Shen, Lu
Ni, Bin
Li, Baohua
Kang, Feiyu
He, Yan-Bing
CHINESE CHEMICAL LETTERS, 2020, 31 (02) : 570 - 574
[8] Cross-Linked Solid Polymer-Based Catholyte for Solid-State Lithium-Sulfur Batteries
Jean-Fulcrand, Annelise
Jeon, Eun Ju
Karimpour, Schahrous
Garnweitner, Georg
BATTERIES-BASEL, 2023, 9 (07):
[9] Sulfur-inserted polymer-anchored edge exfoliated graphite for durable positive electrodes for lithium-sulfur batteries
Uesugi, Nanami
Kazahaya, Natsuho
Yamada, Koki
Kojo, Seiya
Yoshitani, Hiroshi
Wada, Takuya
Fukui, Hiroji
Nozato, Shoji
Katayama, Yu
Tsutsumi, Hiromori
RSC ADVANCES, 2021, 11 (29) : 18093 - 18102
[10] The surface modification of the separator for electrocatalyst in lithium-sulfur batteries
Yu Yu
Zejing Lin
Wenlong Huang
Huitian Liu
Yuansheng Liu
Zhongqiang Shan
Ionics, 2020, 26 : 1129 - 1138

← 1 2 3 4 5 →