Leiyemudanosides A-C, three new bidesmosidic triterpenoid saponins from the roots of Caulophyllum robustum

被引:7
|
作者
Li, Guoyu [1 ,2 ]
Zhang, Yanhai [3 ]
Yang, Bingyou [1 ]
Xia, Yonggang [1 ]
Zhang, Yanlong [4 ]
Lu, Shaowa [1 ]
Kuang, Haixue [1 ]
机构
[1] Heilongjiang Univ Chinese Med, Pharmaceut Coll, Harbin 150040, Peoples R China
[2] Harbin Med Coll, Pharmaceut Coll, Harbin 150086, Peoples R China
[3] Jiangsu Prov Ctr Chinese Med Qual Control, Nanjing 211100, Peoples R China
[4] Heilongjiang Univ, Coll Life Sci, Harbin 150080, Peoples R China
关键词
Berberidaceae; Caulophyllum robustum Maxim; Bidesmoside triterpenoid saponins; Leiyemudanosides A-C; THALICTROIDES; ALKALOIDS; RHIZOMES;
D O I
10.1016/j.fitote.2009.08.025
中图分类号
R914 [药物化学];
学科分类号
100701 ;
摘要
Three new oleanane bidesmosidic triterpenoid saponins, named leiyemudanosides A-C (1-3) were isolated from the roots of Caulophyllum robustum Maxim Their structures were established by chemical and detailed spectroscopic analysis as 3-O-alpha-L-arabinopyranosyl-caulophyllogenin-28-O-beta-D-glucopyranosyl-(1 -> 6)-beta-D-glucopyranosyl ester (1), 3-O-beta-D-glucopyranosyl-(1 -> 3)-alpha-L-arabinopyranosyl-caulophyllogenin-28-O-alpha-L-rhamnopyranosyl-(1 -> 4)-beta-D-glucopyranosyl-(1 -> 6)-beta-D-glucopyranosyl ester (2), and 3-O-beta-D-glucopyranosyl-(1 -> 3)-alpha-L-arabinopyranosyl-echinocyctic acid-28-O-alpha-L-rhamnopyranosyl-(1 -> 4)-beta-D-glucopyranosyl-(1 -> 6)-beta-D-glucopyranosyl ester (3), respectively (C) 2009 Elsevier B V. All rights reserved
引用
收藏
页码:200 / 204
页数:5
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