Study on synthesis of organic light emitting diode materials of aminoanthrancenes and their light emitting property

被引:0
|
作者
Yu, MX [1 ]
Chen, XH
Cheng, CH
机构
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
[2] Tsinghua Univ, Dept Chem, Beijing 30043, Peoples R China
关键词
palladium catalyst; arylamine; aminoanthrancene; tri-tert-butylphosphine;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The primary arylamines reacted with arylhalides to give the secondary arylamines by the catalysis of Pd(dba)(2)/P(t-Bu)(3) at 80 V in toluene. The secondary arylamines reacted with bromoanthrancenes to afford the organic light emitting diode materials of aminoanthrancene type by the catalysis of Pd(OAc)(2)/P(t-BU)(3) at 120 degreesC in o-xylene. The product structures were demonstrated by H-1 NMR, C-13 NMR, C-13 (DEPT) and HRMS spectra. Physical properties were examined by UV-Vis, PL and DSC spectra.
引用
收藏
页码:218 / 221
页数:4
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