Preparation of nanoporous molecular based solid produced by tris-2,2'-biimidazolate Co-III complexes

被引：9

作者：

Tadokoro, M

Shiomi, T

Shiromizu, T

Isobe, K

Matsumoto, K

Nakasuji, K

机构：

[1] OSAKA CITY UNIV, FAC SCI, DEPT MAT SCI, SUMIYOSHI KU, OSAKA 558, JAPAN

[2] OSAKA UNIV, FAC SCI, DEPT CHEM, TOYONAKA, OSAKA 560, JAPAN

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1997年 / 306卷

关键词：

D O I：

10.1080/10587259708044571

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The [Co-III(Hbim)(3)] ((1) under bar) (Hbim = 2,2'-biimidazolate monoanion) is synthesized and its crystal structure is characterizcd by X-ray crystal analysis. (Crystal data: monoclinic, C2/m (No. 12), FW = 970.71, a = 17.144(5) Angstrom, b = 30.341(6) Angstrom, c = 16.422(5) Angstrom, beta = 104.38(2)degrees, V = 8274(3) Angstrom(3), Z = 8). The crystal structure comprises assemblies of two-dimensional honeycomb sheet structures built Lip by alternate arrangements of Delta and Delta binary optical isomers of the building block (1) under bar. The two-dimensional sheets are formed by complementary intermolecular hydrogen bonds of Hbim(-) ligands containing the building block (1) under bar, interestingly, two-dimensional sheets is stacked along c axis to form the microporous crystal with large channels.

引用

页码：235 / 239

页数：5

共 39 条

[1] Preparation of nanoporous molecular based-solid produced by tris-2,2′-biimidazolate CoIII complexes
Tadokoro, Makoto
Shiomi, Takumasa
Shiromizu, Tomoko
Isobe, Kiyoshi
Matsumoto, Keiji
Nakasuji, Kazuhiro
Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, 1997, 306 : 235 - 239
[2] THE PREPARATION OF THE ENANTIOMORPHOUS FORMS OF THE TRIS-2,2'-DIPYRIDYL OSMIUM(III) ION
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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (05) : 2322 - 2323
[3] THE PREPARATION AND COLOUR OF TRIS-2,2'-BIPYRIDYLRHODIUM(III) AND BIS-2,2',2''-TERPYRIDYLRHODIUM(III) SALTS
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[4] THE PREPARATION OF THE OPTICAL FORMS OF TRIS-2,2'-DIPYRIDYL IRON(III) AND TRIS-1,10-PHENANTHROLINE OSMIUM(III) PERCHLORATES
DWYER, FP
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[6] OUTER-SPHERIC COMPLEXES OF COBALT(III) TRIS-2,2'-BIPYRIDINE AND TRIS-1,10-PHENANTHROLINE WITH UNINEGATIVE ANIONS IN AQUEOUS-SOLUTIONS
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INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 97 (02): : 129 - 134
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WATTS, RJ
HARRINGTON, JS
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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (07) : 2179 - 2187
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