Non-isothermal kinetics of spin crossover

被引：8

作者：

Bushuev, Mark B. ^{[1
,2
]}

Nikolaenkova, Elena B. ^{[3
]}

Krivopalov, Viktor P. ^{[3
]}

机构：

[1] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, 3 Acad Lavrentiev Ave, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, 2 Pirogova Str, Novosibirsk 630090, Russia

[3] Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, 9 Acad Lavrentiev Ave, Novosibirsk 630090, Russia

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2017年 / 19卷 / 26期

基金：

俄罗斯基础研究基金会;

关键词：

LARGE THERMAL HYSTERESIS; IRON(II) COMPLEXES; ACTIVATION-ENERGY; TRANSITION; STATE; INTERPLAY; TEMPERATURE; LIGANDS;

D O I：

10.1039/c7cp03442c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Non-isothermal magnetic studies can be used to estimate the activation energy of cooperative spin transition. Model-free isoconversional integral methods give reliable estimates of the activation barrier height for highly cooperative spin crossover systems with wide thermal hysteresis.

引用

页码：16955 / 16959

页数：5

共 50 条

[1] Relationship between non-isothermal transformation curves and isothermal and non-isothermal kinetics
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[2] KINETICS OF NON-ISOTHERMAL PROCESSES
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NATURE-PHYSICAL SCIENCE, 1971, 232 (28): : 41 - +
[3] KINETICS OF NON-ISOTHERMAL DECOMPOSITIONS
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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1966, 5 (10) : 903 - &
[4] KINETICS OF NON-ISOTHERMAL CRYSTALLIZATION
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[5] ON KINETICS OF NON-ISOTHERMAL ADSORPTION
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[6] KINETICS OF NON-ISOTHERMAL CRYSTALLIZATION
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[7] Kinetics of non-isothermal crystallization
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[8] KINETICS OF NON-ISOTHERMAL PLASMA
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[9] NON-ISOTHERMAL KINETICS OF DYEING
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[10] The kinetics of dyeing: a non-isothermal approach
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