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A supramolecular polymer gel with dual-responsiveness constructed by crown ether based molecular recognition
被引:16
|作者:
Xia, Danyu
[1
]
Xue, Min
[1
]
机构:
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China
基金:
中国国家自然科学基金;
中国博士后科学基金;
关键词:
SELF-SORTING ORGANIZATION;
CROSS-LINKED NETWORKS;
DAISY CHAIN;
STIMULI-RESPONSIVENESS;
HYPERBRANCHED POLYMERS;
SHAPE-PERSISTENT;
DRUG-DELIVERY;
GUEST;
DRIVEN;
HOST;
D O I:
10.1039/c4py00590b
中图分类号:
O63 [高分子化学(高聚物)];
学科分类号:
070305 ;
080501 ;
081704 ;
摘要:
A supramolecular polymer gel was prepared by self-assembly of a heteroditopic A-B monomer based on benzo[18]crown-6. Such a gel shows interesting gel-sol transition in response to dual-stimuli owing to the dynamically reversible complexation between the benzo[18]crown-6 and primary alkylammonium salt moieties. Therefore, these fascinating properties make this supramolecular gel a promising intelligent material.
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页码:5591 / 5597
页数:7
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