Polymorphism and thermal behaviour of syndiotactic poly (propylene)/carbon nanotube composites

被引:46
|
作者
Sarno, M [1 ]
Gorrasi, G [1 ]
Sannino, D [1 ]
Sorrentino, A [1 ]
Ciambelli, P [1 ]
Vittoria, V [1 ]
机构
[1] Univ Salerno, Dipartimento Ingn Chim & Alimentare, I-84084 Fisiciano, SA, Italy
关键词
carbon nanotubes; morphology; nanocomposites; poly(propylene) (PP); thermal properties;
D O I
10.1002/marc.200400344
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Nanocomposite materials were obtained by blending multi-wall carbon nanotubes (CN), obtained by acetylene catalytic chemical vapour deposition (CVD) on Co/Fe-modified NaY zeolite, with syndiotactic poly(propylene) (sPP). The nanotubes, well dispersed in the polymer matrix, favour the crystallization of the sPP helical chains and significantly improve the sPP thermal stability either in nitrogen or in air. The morphology of the sPP affects the behaviour of the sPP degradation in air.
引用
收藏
页码:1963 / 1967
页数:5
相关论文
共 50 条
  • [1] Thermal degradation and flammability properties of poly(propylene)/carbon nanotube composites
    Kashiwagi, T
    Grulke, E
    Hilding, J
    Harris, R
    Awad, W
    Douglas, J
    MACROMOLECULAR RAPID COMMUNICATIONS, 2002, 23 (13) : 761 - 765
  • [2] Elastic behaviour of oriented syndiotactic poly(propylene)
    D 'Aniello, C
    Guadagno, L
    Naddeo, C
    Vittoria, V
    MACROMOLECULAR RAPID COMMUNICATIONS, 2001, 22 (02) : 104 - 108
  • [3] Synthesis and properties of syndiotactic poly (propylene)/carbon nanofiber and nanotube composites prepared by in situ polymerization with metallocene/MAO catalysts
    Wiemann, K
    Kaminsky, W
    Gojny, FH
    Schulte, K
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2005, 206 (15) : 1472 - 1478
  • [4] Microwave enhancement of elasticity in poly(propylene)-carbon nanotube composites
    Yoshida, S
    Mitsumata, T
    Sano, M
    CHEMISTRY LETTERS, 2006, 35 (03) : 262 - 263
  • [5] Morphological, Thermal, and Electrical Characterization of Syndiotactic Polypropylene/Multiwalled Carbon Nanotube Composites
    Pollatos, E.
    Logakis, E.
    Chatzigeorgiou, P.
    Peoglos, V.
    Zuburtikudis, I.
    Gjoka, M.
    Viras, K.
    Pissis, P.
    JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS, 2010, 49 (05): : 1044 - 1056
  • [6] Thermal stability of poly(ε-caprolactone)/carbon nanotube composites
    Kim, Hun-Sik
    Park, Byung Hyun
    Kang, Minsung
    Jin, Hyoung-Joon
    Yoon, Jin-San
    ADVANCES IN COMPOSITE MATERIALS AND STRUCTURES, PTS 1 AND 2, 2007, 334-335 : 881 - +
  • [7] Preparation, crystallization, electrical conductivity and thermal stability of syndiotactic polystyrene/carbon nanotube composites
    Sun, Guoxing
    Chen, Guangming
    Liu, Zhengping
    Chen, Ming
    CARBON, 2010, 48 (05) : 1434 - 1440
  • [8] AN INVESTIGATION ON THE STRUCTURE AND THERMAL-BEHAVIOR OF SYNDIOTACTIC POLY(PROPYLENE)
    MARIGO, A
    MAREGA, C
    ZANNETTI, R
    CELLI, A
    PAGANETTO, G
    MACROMOLECULAR RAPID COMMUNICATIONS, 1994, 15 (03) : 225 - 232
  • [9] Polymorphism and transcrystallization of syndiotactic polystyrene composites filled with carbon nanotubes
    Huang, Chien-Lin
    Wang, Chi
    EUROPEAN POLYMER JOURNAL, 2011, 47 (11) : 2087 - 2096
  • [10] Rheological behaviour and mechanical characterization of injectable poly(propylene fumarate)/single-walled carbon nanotube composites for bone tissue engineering
    Shi, XF
    Hudson, JL
    Spicer, PP
    Tour, JM
    Krishnamoorti, R
    Mikos, AG
    NANOTECHNOLOGY, 2005, 16 (07) : S531 - S538