New ionic phosphite ligands: synthesis and application in asymmetric Rh-catalyzed hydrogenation

被引：2
|
作者：
Lyubimov, S. E. [1 ]
Petrovskii, P. V. [1 ]
Davankov, V. A. [1 ]
机构：
[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2009年 / 58卷 / 03期
关键词：
ionic phosphites; rhodium complexes; asymmetric hydrogenation; PHOSPHORAMIDITE LIGANDS; EFFICIENT LIGANDS; PRACTICAL LIGANDS; AMINO-ACIDS;
D O I：
10.1007/s11172-009-0051-1
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A series of chiral ionic phosphite-type ligands bearing pyridinium and imidazolium fragments were prepared. Testing of these ligands in Rh-catalyzed asymmetric hydrogenation of dimethyl itaconate and methyl 2-acetamidoacrylate resulted in 95% ee of the products with 100% conversion of the reactants.
引用
收藏
页码：528 / 531
页数：4
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