One pot catalytic conversion of cellulose into biodegradable surfactants

被引：81
|
作者：
Villandier, Nicolas [1 ]
Corma, Avelino [1 ]
机构：
[1] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain
来源：
CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 24期
关键词：
HYDROLYSIS; DEPOLYMERIZATION; DISSOLUTION; GLUCOSIDES; BIOMASS; FUELS;
D O I：
10.1039/c0cc00031k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Cellulose has been directly converted into environmentally friendly alkyl glycoside surfactants in a one pot transformation. By working in ionic liquid media with Amberlyst 15Dry (A15) as catalyst and coupling the rate of cellulose hydrolysis and the rate of glycosidation of the monosaccharides formed with C4 to C8 alcohols, it was possible to obtain 82% mass yield of octyl-alpha,beta-glucoside plus octyl-alpha,beta-xyloside.
引用
收藏
页码：4408 / 4410
页数：3
相关论文
共 50 条
  • [1] One-pot catalytic conversion of cellulose into polyols with Pt/CNTs catalysts
    Yang, Li
    Yan, Xiaopei
    Wang, Qiwu
    Wang, Qiong
    Xia, Haian
    CARBOHYDRATE RESEARCH, 2015, 404 : 87 - 92
  • [2] One-Pot Catalytic Conversion of Cellulose and of Woody Biomass Solids to Liquid Fuels
    Matson, Theodore D.
    Barta, Katalin
    Iretskii, Alexei V.
    Ford, Peter C.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (35) : 14090 - 14097
  • [3] One-Pot Solvothermal Synthesis of Graphene Nanocomposites for Catalytic Conversion of Cellulose to Ethylene Glycol
    Zhang, Kai
    Yang, Guihua
    Lyu, Gaojin
    Jia, Zhixin
    Lucia, Lucian A.
    Chen, Jiachuan
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (13) : 11110 - 11117
  • [4] A weakly basic Co/CeOx catalytic system for one-pot conversion of cellulose to diols: Kungfu on eggs
    Li, Chuang
    Xu, Guangyue
    Li, Kui
    Wang, Chenguang
    Zhang, Ying
    Fu, Yao
    CHEMICAL COMMUNICATIONS, 2019, 55 (53) : 7663 - 7666
  • [5] One-pot Catalytic Conversion of Cellulose to Sorbitol and Isosorbide over Bifunctional Ni/TaOPO4 Catalysts
    Wu, Yuchen
    He, Minyao
    Liu, Xuefei
    Wang, Xincheng
    Song, Yongji
    Li, Cuiqing
    Liu, Shanshan
    Huang, Long
    CHEMISTRYSELECT, 2022, 7 (28):
  • [6] One-pot catalytic conversion of cellulose to ethylene glycol and other chemicals: From fundamental discovery to potential commercialization
    Zheng, Mingyuan
    Pang, Jifeng
    Wang, Aiqin
    Zhang, Tao
    CHINESE JOURNAL OF CATALYSIS, 2014, 35 (05) : 602 - 613
  • [7] Cellulose-based biodegradable polymeric surfactants
    Talaba, P
    Srokova, I
    Ebringerova, A
    Hodul, P
    Marcincin, A
    JOURNAL OF CARBOHYDRATE CHEMISTRY, 1997, 16 (4-5) : 573 - 582
  • [8] Reaction Network upon One-pot Catalytic Conversion of Pulp
    Ahlkvist, Johan
    Ajaikumar, Samikannu
    Larsson, William
    Warna, Johan
    Salmi, Tapio
    Mikkola, Jyri-Pekka
    ICHEAP-11: 11TH INTERNATIONAL CONFERENCE ON CHEMICAL AND PROCESS ENGINEERING, PTS 1-4, 2013, 32 : 649 - 654
  • [9] One-pot hydrothermal catalytic conversion microalgae into bulk chemicals
    Kong, Lingzhao
    Sun, Yuhan
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 254
  • [10] Catalytic features of Nb-based nanoscopic inorganic fluorides for an efficient one-pot conversion of cellulose to lactic acid
    Verziu, Marian
    Serano, Marion
    Jurca, Bogdan
    Parvulescu, Vasile I.
    Coman, Simona M.
    Scholz, Gudrun
    Kemnitz, Erhard
    CATALYSIS TODAY, 2018, 306 : 102 - 110
12345