Two-dimensional 18-crown-6 complex, [Na2(18-C-6)2(H2O)3]-[Ni(dmit)2]2•(18-C-6), assembled by S•••S and Ni•••S weak interactions

被引：0

作者：

He, GF ^{[1
]}

Wang, DQ ^{[1
]}

Dou, JM ^{[1
]}

Li, DC ^{[1
]}

机构：

[1] Liaocheng Univ, Dept Chem, Liaocheng 252059, Shandong Prov, Peoples R China

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2004年 / 43卷 / 11期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel two-dimensional 18-crown-6 (18-C-6) complex, [Na-2(18-C-6)(2)(H2O)(3)][Ni(dmit)(2)](2)(.)(18-C-6) (dmit, 4,5-dimereapto-1,3-dithiole-2-thione, C3S52-) (1) has been synthesized and characterized by elemental analysis, IR spectrum and X-ray diffraction analysis. I belongs to triclinic, space group P-1 with cell dimensions, a = 13.227(10), b = 12.8421(11), c = 13.8671(12) Angstrom, alpha = 83.715(2), beta = 88.477(2), gamma = 71.850(2)degrees, V = 1904.5(3) Angstrom (3) Z = 2, D-calcd = 1.566 g/cm(3), F(000) = 932, R-1 = 0.0415, wR(2) = 0.0805. It consists of one [Na-2(18-C-6)(2)(H2O)(3)](2+) complex cation, two [Ni(dmit)(2)](-) complex anions and Due free 18-C-6 molecule. The complex shows two-dimensional structure assembled by (SS)-S-... and (NiS)-S-... weak interactions.

引用

页码：2343 / 2346

页数：4

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