Synthesis and crystal structure of [Cu(4-OOCC6H4CN)2 (4-HOOCC6H4CN)(H2O)2] • 2(4-HOOCC6H4CN):: a hydrogen bonded assembly of the first transition metal complex of 4-cyanobenzoic acid

被引：10
|
作者：
Wang, MS
Cai, LZ
Zhou, GW
Guo, GC [1 ]
Huang, JS
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China
[2] Grad Sch Chinese Acad Sci, Beijing, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 07期
关键词：
4-cyanobenzoic acid; Cu(II) complex; hydrogen bonding; carboxylic dimer synthon;
D O I：
10.1016/S1387-7003(03)00121-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The first transition metal complex of 4-cyanobenzoic acid, [Cu(4-OOCC6H4CN)(2)(4-HOOCC6H4CN)(H2O)(2)]. 2(4-HOOCC6H4CN), has been prepared in aqueous medium. X-ray single crystal structure analysis reveals that it is a monometallic complex. Five-coordination Cu(II) ion is approximately in a square based pyramidal environment. Three-dimensional network of this compound is formed through O-H...N, O-H...O, C-H...O and C-H...N hydrogen bonding interactions, yielding a grid framework containing dimers of 4-cyanobenzoic acid with carboxylic dimer 2synthons locating in the channels. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：855 / 858
页数：4
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