Synthesis of enantiomerically pure carbohydrate-derived annulated cyclopentadienes and of a ferrocene

被引：3

作者：

Widauer, C ^{[1
]}

Bernet, B ^{[1
]}

Vasella, A ^{[1
]}

机构：

[1] ETH Zentrum, Organ Chem Lab, CH-8092 Zurich, Switzerland

来源：

SYNTHETIC COMMUNICATIONS | 1998年 / 28卷 / 04期

关键词：

D O I：

10.1080/00397919808005930

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1,3,4,6-Tetra-O-methyl-D-mannitol (3) was synthesized on a large scale in five steps from D-mannitol. Its dimesylate 4 reacted with cyclopentadienyl-sodium to the spiro[4,4]nona-1,3-diene 5. Thermolysis of 5 at 180 degrees gave a mixture of the three tetrahydroindenes 6a/6b/6c which were transformed into the ferrocene 7. The structure of 7 was established by X-ray analysis.

引用

页码：593 / 602

页数：10

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