Advances in stimuli-responsive polymeric coatings for open-tubular capillary electrochromatography

被引：14
|
作者：
Qi, Li [1 ,2 ]
Qiao, Juan [1 ,2 ]
机构：
[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Analyt Chem Living Biosyst, Beijing 100190, Peoples R China
[2] Univ Chinese Acad Sci, Sch Chem Sci, 19A Yuquanlu, Beijing 100049, Peoples R China
来源：
JOURNAL OF CHROMATOGRAPHY A | 2022年 / 1670卷
基金：
中国国家自然科学基金;
关键词：
Open-tubular capillary; electrochromatography; Stimuli-responsive polymeric coatings; Coated capillary; Separation efficiency improvement; Review; BLOCK-COPOLYMERS; SEPARATION; BRUSHES; MEMBRANE; PHASE; IMMOBILIZATION; PERFORMANCE; COLUMNS; GLUCOSE; SURFACE;
D O I：
10.1016/j.chroma.2022.462957
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
Open-tubular capillary electrochromatography (OT-CEC) is an important tool in separation science due to its effective performance and reusability, and has attracted attention because the coating-process and the coating thickness can be controlled. Although dozens of OT-CEC reviews have been published recently, design of the smart polymer coatings, which can improve the separation efficiency of OT-CEC via external stimuli, remains a challenge. This review describes the advancement of research on OT-CEC stimuli-responsive polymeric coatings (SR-PCs). It covers the latest researches in the design and synthesis of stimuli-responsive polymers, the protocols for their fabrication on capillary inner surfaces, strategies for improving stimuli-responsive OT-CEC separation efficiency and real-world applications. (c) 2022 Elsevier B.V. All rights reserved.
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页数：8
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