Sterically controlled azomethine ylide cycloaddition polymerization of phenyl-C61-butyric acid methyl ester

被引：18

作者：

Stephen, Meera ^{[1
,2
]}

Ramanitra, Hasina H. ^{[1
]}

Silva, Hugo Santos ^{[1
,3
]}

Dowland, Simon ^{[4
]}

Begue, Didier ^{[3
]}

Genevicius, Kristijonas ^{[2
]}

Arlauskas, Kestutis ^{[2
]}

Juska, Gytis ^{[2
]}

Morse, Graham E. ^{[5
]}

Distler, Andreas ^{[4
]}

Hiorns, Roger C. ^{[6
]}

机构：

[1] UPPA, EPCP, IPREM, CNRS UMR 5254, 2 Ave President Angot, F-64053 Pau, France

[2] Vilnius Univ, Dept Solid State Elect, Vilnius, Lithuania

[3] UPPA, IPREM, ECP, CNRS UMR 5254, 2 Ave President Angot, F-64053 Pau, France

[4] Belectr OPV GmbH, Landgrabenstr 94, D-90443 Nurnberg, Germany

[5] Merck Chem Ltd, Chilworth Tech Ctr, Univ Pkwy, Southampton SO16 7QD, Hants, England

[6] CNRS, IPREM, EPCP, CNRS UMR 5254, F-64053 Pau, France

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 36期

关键词：

SOLAR-CELLS; FULLERENE POLYMERS; DESIGN RULES; POLY(3-HEXYLTHIOPHENE); DONORS; C-60;

D O I：

10.1039/c6cc01380e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Phenyl-C-61-butyric acid methyl ester (PCBM) is polymerized simply using a one-pot reaction to yield soluble, high molecular weight polymers. The sterically controlled azomethine ylide cycloaddition polymerization (SACAP) is demonstrated to be highly adaptable and yields polymers with probable M-n approximate to 24 600 g mol(-1) and M-w approximate to 73800 g mol(-1). Products are metal-free and of possible benefit to organic and hybrid photovoltaics and electronics as they form thin films from solution and have raised LUMOs. The promising electronic properties of this new polymer are discussed.

引用

页码：6107 / 6110

页数：4

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