P*-chiral phosphapalladacycle as derivatizing agent for enantiomeric purity determination of α-amino acids by means of 31P NMR spectroscopy

被引:39
|
作者
Dunina, VV [1 ]
Gorunova, ON [1 ]
Livantsov, MV [1 ]
Grishin, YK [1 ]
机构
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia
关键词
D O I
10.1016/S0957-4166(00)00221-4
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A P*-chiral cyclopalladated complex was shown to be an efficient chiral derivatizing agent for enantiomeric excess determination of alpha-amino acids by P-31 NMR technique. The main advantages of this type of reagent are discussed. (C) 2000 Elsevier Science Ltd. All rights reserved.
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页码:2907 / 2916
页数:10
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