The high-energy intraconfigurational spin-forbidden bands in the spectra of quadrate chromium(III) complexes

被引：1
|
作者：
Williams, C. S. [1 ]
Miller, N. C. [1 ]
Perumareddi, J. R. [1 ]
机构：
[1] Florida Atlantic Univ, Dept Chem, Boca Raton, FL 33431 USA
来源：
INORGANICA CHIMICA ACTA | 2007年 / 360卷 / 08期
关键词：
spin-forbidden bands; chromium(III) complexes;
D O I：
10.1016/j.ica.2007.01.005
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The high-energy intraconfigurational spin-forbidden bands expected in the region of 20000 cm(-1) have been uncovered in the spectra of a number of trans-diacidobis(ethylenediamine) chromium(III)complexes. These bands have been fitted to the quadrate components of the cubic transition (4)A(2g)-> T-2(2g) including spin-orbit interaction. Two interconfigurational spin-forbidden bands in the spectrum of trans-[Cr(en)(2)(dmf)(2)](ClO4)(3) have been uncovered and interpretted. (C) 2007 Elsevier B.V. All rights reserved.
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页码：2842 / 2845
页数：4
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