Iodine(III)-catalyzed benzylic oxidation by using the (PhIO)n/Al(NO3)3 system

被引：22

作者：

Yahuaca-Juarez, Berencie ^{[1
]}

Gonzalez, Gerardo ^{[2
]}

Ramirez-Morales, Marco A. ^{[2
]}

Alba-Betancourt, Calara ^{[2
]}

Deveze-Alvarez, Martha A. ^{[2
]}

Mendoza-Macias, Claudia L. ^{[2
]}

Ortiz-Alvarado, Rafael ^{[1
]}

Juarez-Ornelas, Kevin A. ^{[2
]}

Solorio-Alvarado, Cesar R. ^{[2
]}

Maruoka, Keiji ^{[3
,4
]}

机构：

[1] Univ Michoacana, Fac Quim Farmacobiol, Morelia, Michoacan, Mexico

[2] Univ Guanajuato, Dept Quim, Divi Ciencias Nat & Exactas, Guanajuato, Mexico

[3] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto, Japan

[4] Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Peoples R China

来源：

SYNTHETIC COMMUNICATIONS | 2020年 / 50卷 / 04期

关键词：

Benzylic oxidation; C-sp(3)-H activation; iodine(III)-catalysis; organocatalyst; C-H OXIDATION; AEROBIC OXIDATION; EFFICIENT; METAL; BROMINATION; TETRALIN; REAGENT; PHENOLS; COPPER; BONDS;

D O I：

10.1080/00397911.2019.1707225

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first iodine(III)-based procedure for the benzylic oxidation of different arenes is described by using the (PhIO)(n)/Al(NO3)(3) system under catalytic conditions leading to the formation of the corresponding carbonyl derivatives. The method proceeds under mild, operationally simple, room temperature, short reaction times, and open flask conditions. In light of the organocatalysis relevance and the novelty of our protocol, we wish to communicate our initial results of this novel oxidation.

引用

页码：539 / 548

页数：10

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