Processes in multicomponent mixtures of chemically reacting gases for nonadiabatic and open uniform thermodynamic systems

被引:0
|
作者
Smirnov, A. I. [1 ]
机构
[1] Academician VP Glushko OAO NPO Energomash, Chimki, Moscow Oblast, Russia
关键词
Reaction rates - Thermal effects - Thermodynamic properties;
D O I
10.1134/S0040579507030074
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
This paper reports the results of chemical-thermodynamic analysis of processes in spatially uniform multicomponent mixtures of chemically reacting gases under the conditions of open nonadiabatic systems, that is, with supply of heat, substance, and external mechanical work. At each trajectory point, it is possible to construct an associate field of the possible states and describe the development of spontaneous chemical process. Note that the reaction rates at these points under the general-type external conditions are governed by the same regularities as those for isolated or isobaric-adiabatic closed system.
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页码:279 / 283
页数:5
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