Lasing in robust cesium lead halide perovskite nanowires

被引:695
|
作者
Eaton, Samuel W. [1 ]
Lai, Minliang [1 ]
Gibson, Natalie A. [1 ,2 ]
Wong, Andrew B. [1 ,3 ]
Dou, Letian [1 ,3 ]
Ma, Jie [3 ,4 ]
Wang, Lin-Wang [3 ,4 ]
Leone, Stephen R. [1 ,2 ,5 ]
Yang, Peidong [1 ,3 ,6 ]
机构
[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[2] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Chem Sci, Berkeley, CA 94720 USA
[3] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Mat Sci, Berkeley, CA 94720 USA
[4] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Joint Ctr Artificial Photosynth, Berkeley, CA 94720 USA
[5] Univ Calif Berkeley, Dept Phys, Berkeley, CA 94720 USA
[6] Kavli Energy NanoSci Inst, Berkeley, CA 94720 USA
关键词
nanowire; perovskite; laser; inorganic; stability; MICROCRYSTALLINE CSPBBR3 FILMS; STIMULATED-EMISSION; PHASE SYNTHESIS; LASERS; NANOCRYSTALS; CSPBX3; BR; CL; CELLS;
D O I
10.1073/pnas.1600789113
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The rapidly growing field of nanoscale lasers can be advanced through the discovery of new, tunable light sources. The emission wavelength tunability demonstrated in perovskite materials is an attractive property for nanoscale lasers. Whereas organic-inorganic lead halide perovskite materials are known for their instability, cesium lead halides offer a robust alternative without sacrificing emission tunability or ease of synthesis. Here, we report the low-temperature, solution-phase growth of cesium lead halide nanowires exhibiting low-threshold lasing and high stability. The as-grown nanowires are single crystalline with well-formed facets, and act as high-quality laser cavities. The nanowires display excellent stability while stored and handled under ambient conditions over the course of weeks. Upon optical excitation, Fabry-Perot lasing occurs in CsPbBr3 nanowires with an onset of 5 mu J cm(-2) with the nanowire cavity displaying a maximum quality factor of 1,009 +/- 5. Lasing under constant, pulsed excitation can be maintained for over 1 h, the equivalent of 109 excitation cycles, and lasing persists upon exposure to ambient atmosphere. Wavelength tunability in the green and blue regions of the spectrum in conjunction with excellent stability makes these nanowire lasers attractive for device fabrication.
引用
收藏
页码:1993 / 1998
页数:6
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