Investigation of the basis of catalytic activity of solid state phosphate complexes in the Knoevenagel condensation

被引：39
|
作者：
Bennazha, J
Zahouilly, M
Boukhari, A
Holt, EM [1 ]
机构：
[1] Oklahoma State Univ, Dept Chem, Stillwater, OK 74078 USA
[2] Univ Hassan 2, Fac Sci & Tech, LMCE, Mohammadia 20650, Morocco
[3] Univ Hassan 2, Fac Sci & Tech, Dept Chim, UFR Chim Appl, Mohammadia 20650, Morocco
[4] Univ Mohammed 5, LSCA, Lab Associe Francophone, Dept Chim,Fac Sci, Rabat, Morocco
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2003年 / 202卷 / 1-2期
关键词：
Knoevenagel condensation; phosphate catalysts; ethyl (E)-alpha-cyanocinnamate; heterogeneous catalysis;
D O I：
10.1016/S1381-1169(03)00208-5
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The Knoevenagel condensation of benzaldehyde and ethyl cyanoacetate in ethanol at ambient temperature was catalyzed with range of mono-, meta- and diphosphate complexes. Comparison of the results shows that the catalytic activity of those phosphates is related to the electropositivity of the cation present in the structure and to the availability of the phosphate moiety to serve as a base. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：247 / 252
页数：6
相关论文
共 50 条
  • [1] Preparation and catalytic property of the solid base supported on the mixed zirconium phosphate phosphonate for Knoevenagel condensation
    Zeng, RQ
    Fu, XK
    Gong, CB
    Sui, Y
    Ma, XB
    Yang, XB
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 229 (1-2) : 1 - 5
  • [2] Comparison of the catalytic activity of MOFs and zeolites in Knoevenagel condensation
    Opanasenko, Maksym
    Dhakshinamoorthy, Amarajothi
    Shamzhy, Mariya
    Nachtigall, Petr
    Horacek, Michal
    Garcia, Hermenegildo
    Cejka, Jiri
    CATALYSIS SCIENCE & TECHNOLOGY, 2013, 3 (02) : 500 - 507
  • [3] Catalytic activity of proton sponge: Application to Knoevenagel condensation reactions
    Rodriguez, I
    Sastre, G
    Corma, A
    Iborra, S
    JOURNAL OF CATALYSIS, 1999, 183 (01) : 14 - 23
  • [4] NATURAL PHOSPHATE AND TRISODIUM PHOSPHATE - NEW SOLID CATALYSTS OF KNOEVENAGEL CONDENSATION IN A HETEROGENEOUS SOLUTION
    SEBTI, S
    SABER, A
    RHIHIL, A
    TETRAHEDRON LETTERS, 1994, 35 (50) : 9399 - 9400
  • [5] Synthesis of KOH/SnO2 solid superbases for catalytic Knoevenagel condensation
    Xie, Jun
    Chen, Lang
    Au, Chak-Tong
    Yin, Shuang-Feng
    CATALYSIS COMMUNICATIONS, 2015, 66 : 30 - 33
  • [6] Improvement of the catalytic performance of hybrid nanocomposite based on phosphate-benzimidazole in Knoevenagel condensation
    Benzekri, Zakaria
    El Aadad, Halima
    Sibous, Sarra
    Serrar, Houda
    Boukhris, Said
    Chahine, Abdelkrim
    Souizi, Abdelaziz
    HELIYON, 2020, 6 (11)
  • [7] Direct synthesis of magnesium doped mesoporous silica: Their catalytic activity in Knoevenagel Condensation
    Nandi, Mahasweta
    Das, Trisha
    Saha, Soumen
    Uyama, Hiroshi
    MATERIALS TODAY-PROCEEDINGS, 2018, 5 (03) : 10007 - 10015
  • [8] Effects of the Nitridation of Y and USY Zeolites on their Catalytic Activity for the Base Catalyzed Knoevenagel Condensation
    Srasra, Mondher
    Delsarte, Stephanie
    Gaigneaux, Eric M.
    TOPICS IN CATALYSIS, 2009, 52 (11) : 1541 - 1548
  • [9] Effects of the Nitridation of Y and USY Zeolites on their Catalytic Activity for the Base Catalyzed Knoevenagel Condensation
    Mondher Srasra
    Stéphanie Delsarte
    Eric M. Gaigneaux
    Topics in Catalysis, 2009, 52 : 1541 - 1548
  • [10] Effect of Amine Modification on Catalytic Activity of ZIF-8 in Knoevenagel Condensation Reaction
    Gao P.
    Wu D.
    Zheng H.
    Chen H.
    Zhang P.
    Hunan Daxue Xuebao/Journal of Hunan University Natural Sciences, 2020, 47 (08): : 124 - 132
12345