Photoactivation of triosmium dodecacarbonyl at 400 nm probed with time-resolved X-ray liquidography

被引：4

作者：

Ki, Hosung ^{[1
,2
,3
]}

Kim, Tae Wu ^{[4
]}

Moon, Jiwon ^{[5
]}

Kim, Jungmin ^{[1
,2
,3
]}

Lee, Yunbeom ^{[1
,2
,3
]}

Heo, Jun ^{[1
,2
,3
]}

Kim, Kyung Hwan ^{[6
]}

Kong, Qingyu ^{[7
]}

Khakhulin, Dmitry ^{[8
]}

Newby, Gemma ^{[9
]}

Kim, Joonghan ^{[5
]}

Kim, Jeongho ^{[10
]}

Wulff, Michael ^{[9
]}

Ihee, Hyotcherl ^{[1
,2
,3
]}

机构：

[1] Inst Basic Sci IBS, Ctr Adv React Dynam, Daejeon 34141, South Korea

[2] Korea Adv Inst Sci & Technol KAIST, Dept Chem, Daejeon 34141, South Korea

[3] Korea Adv Inst Sci & Technol KAIST, KI BioCentury, Daejeon 34141, South Korea

[4] Mokpo Natl Univ, Dept Chem, Muan Gun 58554, Jeollanam Do, South Korea

[5] Catholic Univ Korea, Dept Chem, Bucheon 14662, South Korea

[6] Pohang Univ Sci & Technol POSTECH, Dept Chem, Pohang 37673, South Korea

[7] Synchrotron Soleil, BP 48, F-91192 Gif Sur Yvette, France

[8] European XFEL, Halzkoppel 4, D-22869 Schenefeld, Germany

[9] European Synchrotron Radiat Facil, BP 220, F-38043 Grenoble, France

[10] Inha Univ, Dept Chem, Incheon 22212, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 53期

关键词：

SOLUTION SCATTERING REVEALS; M-3(CO)(12) M; OS3(CO)12; CLUSTERS; DYNAMICS; PHOTOCHEMISTRY; PHOTOREACTIONS; RU-3(CO)(12); REACTIVITY; PHOTOLYSIS;

D O I：

10.1039/d2cc02438a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photoactivation mechanism of Os-3(CO)(12) at 400 nm is examined with time-resolved X-ray liquidography. The data reveal two pathways: the vibrational relaxation following an internal conversion to the electronic ground state and the ligand dissociation to form Os-3(CO)(11) with a ligand vacancy at the axial position.

引用

页码：7380 / 7383

页数：4

共 50 条

[1] Optical Kerr Effect of Liquid Acetonitrile Probed by Femtosecond Time-Resolved X-ray Liquidography
Ki, Hosung
Choi, Seungjoo
Kim, Jungmin
Choi, Eun Hyuk
Lee, Seonggon
Lee, Yunbeom
Yoon, Kihwan
Ahn, Chi Woo
Ahn, Doo-Sik
Lee, Jae Hyuk
Park, Jaeku
Eom, Intae
Kim, Minseok
Chun, Sae Hwan
Kim, Joonghan
Ihee, Hyotcherl
Kim, Jeongho
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021, 143 (35) : 14261 - 14273
[2] Revealing structural dynamics of proteins with time-resolved x-ray liquidography
Ihee, Hyotcherl
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2021, 77 : A81 - A81
[3] Gold Nanoparticle Formation via X-ray Radiolysis Investigated with Time-Resolved X-ray Liquidography
Ki, Hosung
Park, Sungjun
Eom, Seunghwan
Gu, Jain
Kim, Siim
Kim, Changwon
Ahn, Chi Woo
Choi, Minseo
Ahn, Sena
Ahn, Doo-Sik
Choi, Jungkweon
Baik, Mu-Hyun
Ihee, Hyotcherl
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2020, 21 (19) : 1 - 16
[4] Spatiotemporal Kinetics in Solution Studied by Time-Resolved X-Ray Liquidography (Solution Scattering)
Kim, Tae Kyu
Lee, Jae Hyuk
Wulff, Michael
Kong, Qingyu
Ihee, Hyotcherl
CHEMPHYSCHEM, 2009, 10 (12) : 1958 - 1980
[5] Visualizing Solution-Phase Reaction Dynamics with Time-Resolved X-ray Liquidography
Ihee, Hyotcherl
ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (02) : 356 - 366
[6] Acoustic phonons in InSb probed by time-resolved X-ray diffraction
Morak, A.
Kaempfer, T.
Uschmann, I.
Luebeke, A.
Foerster, E.
Sauerbrey, R.
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2006, 243 (12): : 2728 - 2744
[7] Coherent control of phonons probed by time-resolved x-ray diffraction
Lindenberg, AM
Kang, I
Johnson, SL
Falcone, RW
Heimann, PA
Chang, Z
Lee, RW
Wark, JS
OPTICS LETTERS, 2002, 27 (10) : 869 - 871
[8] Photochemistry of HgBr2 in methanol investigated using time-resolved X-ray liquidography
Jun, Sunhong
Lee, Jae Hyuk
Kim, Jeongho
Kim, Joonghan
Kim, Kyung Hwan
Kong, Qingyu
Kim, Tae Kyu
Lo Russo, Manuela
Wulff, Michael
Ihee, Hyotcherl
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2010, 12 (37) : 11536 - 11547
[9] Ultrafast structural dynamics in InSb probed by time-resolved x-ray diffraction
Chin, AH
Schoenlein, RW
Glover, TE
Balling, P
Leemans, WP
Shank, CV
PHYSICAL REVIEW LETTERS, 1999, 83 (02) : 336 - 339
[10] Ultrafast structural dynamics in InSb probed by time-resolved X-ray diffraction
Chin, AH
Schoenlein, RW
Glover, TE
Balling, P
Leemans, WP
Shank, CV
ULTRAFAST PHENOMENA XI, 1998, 63 : 401 - 403

← 1 2 3 4 5 →