Retained molten salt electrolytes in thermal batteries

被引:31
|
作者
Masset, P
Schoeffert, S
Poinso, JY
Poignet, JC
机构
[1] Ctr Etud Ripault, Commissariat Energie Atom, F-37260 Monts, France
[2] ASB Aerospatiale Batteries, F-18021 Bourges, France
[3] Ecole Natl Super Electrochim & Electrome Grenoble, Inst Natl Polytech Grenoble, Lab Electrochim & Physicochim Mat & Interfaces, F-38402 St Martin Dheres, France
关键词
electrolyte; retention; thermal battery; MgO magnesia;
D O I
10.1016/j.jpowsour.2004.07.009
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In high temperature electrical generators such as thermal batteries, the molten salt electrolyte needs to be retained by a binder, e.g. MgO. We have pointed out that the magnesia volume fraction was a more accurate parameter than the usually used weight fraction. Moreover, based on our technique measurements, we defined a magnesia volume fraction range (27-30 vol.%) where the electrolyte retention could be considered as efficient whatever its nature. And finally, we proposed a microstructure description of the retained electrolyte. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:356 / 365
页数:10
相关论文
共 50 条
  • [1] Ion Transport in MgO Porous Fibers Retained Molten Salt Electrolytes for Thermal Batteries
    Zeng, Mengshi
    Liu, Jingsong
    Yang, Zhaotang
    Liu, Xiaojiang
    Wang, Fu
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2018, 165 (05) : A736 - A740
  • [2] Molecular Dynamics Analysis of High-temperature Molten-salt Electrolytes in Thermal Batteries
    Chen, C. F.
    Li, H. Y.
    Hong, C. W.
    CMC-COMPUTERS MATERIALS & CONTINUA, 2015, 46 (03): : 145 - 163
  • [3] Molecular dynamics analysis of high-temperature molten-salt electrolytes in thermal batteries
    Department of Power Mechanical Engineering, National Tsing Hua University, Hsinchu
    30013, Taiwan
    Comput. Mater. Continua, 3 (145-163):
  • [4] Electrodes and electrolytes for molten salt batteries: Expanding the temperature regimes
    Carlin, RT
    Fuller, J
    MOLTEN SALTS: FROM FUNDAMENTALS TO APPLICATIONS, 2002, 52 : 321 - 344
  • [5] Thermal Stability of FeS2 Cathode Material in "Thermal" Batteries: Effect of Dissolved Oxides in Molten Salt Electrolytes
    Masset, Patrick J.
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 2008, 63 (09): : 596 - 602
  • [6] ac impedance measurements of molten salt thermal batteries
    Singh, P
    Guidotti, RA
    Reisner, D
    JOURNAL OF POWER SOURCES, 2004, 138 (1-2) : 323 - 326
  • [7] Effect of impurities (oxides, hydroxides) in molten salt electrolytes on the thermal stability of FeS2 cathode material for thermal batteries
    Masset, Patrick J.
    HIGH TEMPERATURE CORROSION AND MATERIALS CHEMISTRY 8, 2010, 25 (25): : 155 - 165
  • [8] On the classification of molten salt electrolytes
    Khokhlov V.A.
    Russian Metallurgy (Metally), 2010, 2010 (2) : 96 - 104
  • [9] ORGANIC AND MOLTEN SALT ELECTROLYTES
    JASINSKI, R
    MECHANICAL ENGINEERING, 1968, 90 (06) : 68 - &
  • [10] Low-temperature thermal batteries using molten nitrate electrolytes
    Niu, Yongqiang
    Zhao, Yuhong
    JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2022, 26 (08) : 1549 - 1556