Efficient Synthesis of Biomass-Derived N-Substituted 2-Hydroxymethyl-5-Methyl-Pyrroles in Two Steps from 5-Hydroxymethylfurfural

被引：24

作者：

Wozniak, Bartosz ^{[1
]}

Li, Yuehui ^{[2
]}

Hinze, Sandra ^{[1
]}

Tin, Sergey ^{[1
]}

de Vries, Johannes G. ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse, Albert Einstein Str 29a, D-18059 Rostock, Germany

[2] Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Suzhou Res Inst LICP, LICP, Lanzhou 730000, Gansu, Peoples R China

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 2018卷 / 17期

关键词：

Pyrroles; Paal-Knorr synthesis; Heterocycles; Cyclization; Renewable resources; PAAL-KNORR REACTION; CATALYTIC CONVERSION; PYRROLE; LIGANDS; DERIVATIVES; COMPLEXES;

D O I：

10.1002/ejoc.201800171

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient two-step synthesis for the conversion of biomass-derived 5-hydroxymethyl-furfural (HMF) to a variety of N-substituted 2-hydroxymethyl-5-methylpyrroles was developed. In the first step, 1-hydroxyhexane-2,5-dione (HHD) was obtained by hydrogenation of HMF and thereafter used in a Paal-Knorr reaction with a range of amines in the absence of catalyst at room temperature. The reaction could potentially be used as a click reaction.

引用

页码：2009 / 2012

页数：4

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