Hydrogen bonded 2,2′-biimidazolate transition metal complexes as a tool of crystal engineering

被引:218
|
作者
Tadokoro, M
Nakasuji, K
机构
[1] Osaka City Univ, Grad Sch Sci, Dept Chem, Sumiyoshi Ku, Osaka 5588585, Japan
[2] Osaka Univ, Grad Sch Sci, Dept Chem, Toyonaka, Osaka 5600043, Japan
关键词
crystal engineering; hydrogen bond; metal complex; nanostructure; supramolecular chemistry;
D O I
10.1016/S0010-8545(99)00223-4
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
In the field of crystal engineering, many attempts have been made to control the molecular arrangements in crystal by simultaneous use of coordination bonds of a transition metal ion and complementary intermolecular hydrogen bonds. We obtained the first crystal structure of the hydrogen bonded metal complex of 2,2'-biimidazolate monoanion ligand Hbim(-) with Cu(II) as a neutral dimer metal complex. The hydrogen-bonded dimer structure indicates that the Hbim(-) ligand controls the crystal structure using not only the coordination to a transition metal ion as a bidentate chelate but simultaneously the formation of complementary intermolecular hydrogen bonds. We also found that the Hbim(-) ligand gave [Ni(Hbim)(3)](-) as a new building block for hydrogen-bonded self-assembling networks by one-pot synthesis to mix Ni(II) ion, counter cation and the ligand. The networks form zero-dimensional, one-dimensional, two-dimensional, and three-dimensional structures depending upon the kind of counter cations. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:205 / 218
页数:14
相关论文
共 50 条
  • [1] DIMERIC HYDROGEN-BONDED TRANSITION-METAL COMPLEX CONTAINING BIDENTATE MONO-DEPROTONATED 2,2'-BIIMIDAZOLATE LIGAND
    TADOKORO, M
    TOYODA, J
    ISOBE, K
    ITOH, T
    MIYAZAKI, A
    ENOKI, T
    NAKASUJI, K
    CHEMISTRY LETTERS, 1995, (08) : 613 - 614
  • [2] Crystal engineering on controlled crystal arrays using hydrogen bonding biimidazolate metal complexes
    Tadokoro, M
    JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 2004, 62 (06) : 629 - 640
  • [3] Synthesis and characterization of complexes of the first transition series cations with 2,2′-biimidazole and 2,2′-biimidazolate
    Barquín, M
    Garmendia, MJG
    Bellido, V
    TRANSITION METAL CHEMISTRY, 2003, 28 (03) : 356 - 360
  • [4] Synthesis and characterization of complexes of the first transition series cations with 2,2′-biimidazole and 2,2′-biimidazolate
    Montserrat Barquín
    María J. González Garmendia
    Víctor Bellido
    Transition Metal Chemistry, 2003, 28 : 356 - 360
  • [5] Double channel structures based on hydrogen bonding networks of 2,2'-biimidazolate nickel(II) complexes
    Tadokoro, M
    Isobe, K
    Nakasuji, K
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1996, 285 : 269 - 274
  • [6] HYDROGEN-TRANSFER CATALYTIC SYNERGISM IN BINUCLEAR COMPLEXES CONTAINING 2,2'-BIIMIDAZOLATE AS A BRIDGING LIGAND
    ESTERUELAS, MA
    GARCIA, MP
    LOPEZ, AM
    ORO, LA
    ORGANOMETALLICS, 1992, 11 (02) : 702 - 705
  • [7] HETEROBINUCLEAR AND HETEROTETRANUCLEAR RURH AND RUIR COMPLEXES WITH 2,2'-BIIMIDAZOLATE AND 2,2'-BIBENZIMIDAZOLATE ANIONS AS BRIDGING LIGANDS
    CARMONA, D
    FERRER, J
    MENDOZA, A
    LAHOZ, FJ
    ORO, LA
    VIGURI, F
    REYES, J
    ORGANOMETALLICS, 1995, 14 (04) : 2066 - 2080
  • [8] Synthesis and crystal structures of six thiocyanato-connected transition metal complexes of 2,2′-biimidazole
    Qiu, Qi-Ming
    Jin, Qiong-Hua
    Sun, Jing-Jing
    Liu, Min
    Wang, Jian-Chun
    Zhang, Yuan-Yuan
    Zhang, Cun-Lin
    POLYHEDRON, 2012, 44 (01) : 215 - 220
  • [9] Metal Complexes of 2,2′-Bipyridine-4,4′-diamine as Metallo-Tectons for Hydrogen Bonded Networks
    Rigby, Nicola
    Jacobs, Tia
    Reddy, Jayarama Prakasha
    Hardie, Michaele J.
    CRYSTAL GROWTH & DESIGN, 2012, 12 (04) : 1871 - 1881
  • [10] COMPLEXES OF 2,2'-BI-2-IMIDAZOLINE WITH TRANSITION METAL IONS
    WANG, JC
    BAUMAN, JE
    INORGANIC CHEMISTRY, 1965, 4 (11) : 1613 - &