Cp(CO)(2)MnN(Bz)CH2CH2, the first mono-coordinate aziridine complex

被引：0

作者：

vonBeckerath, S

Lorenz, IP

Fawzi, R

Steimann, M

机构：

[1] UNIV MUNICH,INST ANORGAN CHEM,D-80333 MUNICH,GERMANY

[2] UNIV TUBINGEN,INST ANORGAN CHEM 2,D-72076 TUBINGEN,GERMANY

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1996年 / 51卷 / 07期

关键词：

N-benzyl-aziridine; substitution; cymantrene; X-ray;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The photolytically induced CO-substitution reaction of CpMn(CO)(3) with N-benzyl-aziridine leads to the first mono coordinate aziridine complex, Cp(CO)(2)MnN(Bz)CH2CH2. It is stable against thermal C2H4 elimination up to 135 degrees C. No nitrene complexes {Cp(CO)(2)Mn}(n)NBz (n = 1, 2) were detected. The X-ray structure analysis of Cp(CO)(2)MnN(Bz)CH2CH2 shows the intact three-membered ring ligand and the pyramidal configuration of the nitrogen atom.

引用

页码：959 / 962

页数：4

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