Poly[[bis(μ2-6-methylpyrazin-2-carboxylato-κ3N1,O:N4)copper(II)] dihydrate]

被引:0
|
作者
Fan, Chuan-gang [2 ]
Wei, Xin-Ting [1 ]
Li, Linwei [1 ]
机构
[1] Liaocheng Univ, Coll Chem & Chem Engn, Liaocheng 252059, Shandong, Peoples R China
[2] Binzhou Univ, Dept Chem & Chem Engn, Binzhou 256603, Shandong, Peoples R China
关键词
D O I
10.1107/S1600536809041440
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, {[Cu(C6H5N2O2)(2)]center dot 2H(2)O}(n), the Cu-II ion (site symmetry (1) over bar) is coordinated by two N,O-bidentate ligands and two N-monodentate ligands in a distorted CuO2N4 octahedral geometry. Each anion acts as a bridge between two cations, thus forming a two-dimensional polymeric network parallel to the ab plane. The packing is consolidated by O-H center dot center dot center dot O hydrogen bonds. One of the O atoms of the ligand and both water molecules are disordered.
引用
收藏
页码:M1412 / U1549
页数:10
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