Structures and Luminescence of Three Cd(II) Dicarboxylate Coordination Polymers

被引：0
|
作者：
Yue Fan [1 ]
Jian Ming-Feng [1 ]
Chen Xiao-Ming [1 ]
机构：
[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, MOE Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 25卷 / 09期
关键词：
metal carboxylate; crystal structure; luminescent properties; CRYSTAL-STRUCTURES; HELICAL CHAINS; MIXED-LIGANDS; PHOTOLUMINESCENCE; ARCHITECTURES; FRAMEWORKS; FLUORESCENCE; NETWORK;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three cadmium(II) dicarboxylate coordination polymers have been synthesized by solvothermal method: [Cd(TP)(DPQ)(H2O)](n). (1), [Cd(IP)(DPPZ)](n) (2) and [Cd(SU)(DPPZ)](n) (3) (TP=terephthalate, IP=isophthalate, SU=succinate, DPQ=pyrazino[2,3-f][1,10]phenanthroline, DPPZ=dipyrido[3,2-a:2',3'-c]phenzine). Among them, 1 and 3 crystallize in the monoclinic space group P2(1)/c, while 2 in C2/c. Luminescent studies show that, with the flexible dicarboxylate, the fluorescence intensity of 3 is much less than that of 1 and 2. CCDC: 725669, 1; 725667, 2; 725668, 3.
引用
收藏
页码：1590 / 1594
页数：5
相关论文
共 17 条
  • [1] [Anonymous], 2000, SHELXTL 6 10
  • [2] ZN4O(ACETATE)6, A WELL-TAILORED MOLECULAR-MODEL OF ZNO - AN EXPERIMENTAL AND THEORETICAL INVESTIGATION OF THE ELECTRONIC-STRUCTURE OF ZN4O(ACETATE)6 AND ZNO BY MEANS OF UV AND X-RAY PHOTOELECTRON SPECTROSCOPIES AND 1ST PRINCIPLE LOCAL DENSITY MOLECULAR CLUSTER CALCULATIONS
    BERTONCELLO, R
    BETTINELLI, M
    CASARIN, M
    GULINO, A
    TONDELLO, E
    VITTADINI, A
    [J]. INORGANIC CHEMISTRY, 1992, 31 (09) : 1558 - 1565
  • [3] Syntheses, structures and photoluminescence of a series of metal-organic complexes with 1,3,5-benzenetricarboxylate and pyrazino[2,3-f][1,10]-phenanthroline ligands
    Che, Guang-Bo
    Liu, Chun-Bo
    Liu, Bo
    Wang, Qing-Wei
    Xu, Zhan-Lin
    [J]. CRYSTENGCOMM, 2008, 10 (02): : 184 - 191
  • [4] Photoluminescent metal-organic polymer constructed from trimetallic clusters and mixed carboxylates
    Chen, W
    Wang, JY
    Chen, C
    Yue, Q
    Yuan, HM
    Chen, JS
    Wang, SN
    [J]. INORGANIC CHEMISTRY, 2003, 42 (04) : 944 - 946
  • [5] Synthesis, structure, and fluorescence of the novel cadmium(II)-trimesate coordination polymers with different coordination architectures
    Dai, JC
    Wu, XT
    Fu, ZY
    Cui, CP
    Hu, SM
    Du, WX
    Wu, LM
    Zhang, HH
    Sun, RO
    [J]. INORGANIC CHEMISTRY, 2002, 41 (06) : 1391 - 1396
  • [6] Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks
    Eddaoudi, M
    Moler, DB
    Li, HL
    Chen, BL
    Reineke, TM
    O'Keeffe, M
    Yaghi, OM
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) : 319 - 330
  • [7] Edelmann MJ, 2002, HELV CHIM ACTA, V85, P2195, DOI 10.1002/1522-2675(200207)85:7<2195::AID-HLCA2195>3.0.CO
  • [8] 2-G
  • [9] Effect of the size of aromatic chelate ligands on the frameworks of metal dicarboxylate polymers: From helical chains to 2-D networks
    Han, ZB
    Cheng, XN
    Chen, XM
    [J]. CRYSTAL GROWTH & DESIGN, 2005, 5 (02) : 695 - 700
  • [10] A cadmium coordination polymer containing helical chains:: catena-poly[[(dipyrido[3,2-a:2′,3′-c]phenazine)cadmium]-μ-benzene-1,3-dicarboxylato]
    Li, Chuan-Bi
    Fang, Wei
    Gao, Guang-Gang
    Liu, Bo
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M1312 - M1314
12