Photocatalytic process for energy recovery in wastewater decontamination

被引:0
|
作者
Canterino, M. [1 ]
Di Somma, I. [1 ]
Marotta, R. [1 ]
Bizzarro, A. [2 ]
Andreozzi, R. [1 ]
Caprio, V. [1 ]
机构
[1] Univ Naples Federico II, Dipartimento Ingn Chim, Ple Tecchio 80, I-80125 Naples, Italy
[2] CNR, Ist Ric Combust, I-80125 Naples, Italy
关键词
TITANIUM-DIOXIDE; METAL-IONS; SUSPENSIONS;
D O I
10.3303/CET0917039
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The contemporary removal of formic acid (FA) from aqueous solution and electricity generation is studied by means of the combination of a photocatalytic reactor and an electrochemical cell. The proposed system relies on the capability of Cu2+ ions to reduce in presence of TiO2, (solar) UV radiations and a sacrificial organic agent. In the anodic solution of the combined photoreactor-cell, Cu-0 is oxidized to Cu2+ due to the cell work and the latter is reduced again to the lowest oxidation state as a result of the photocatalytic process. The use of different sacrificial agents such as formic acid (FA) and glycerol (GLY) is investigated.
引用
收藏
页码:227 / +
页数:2
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