Poly(ethylene Glycol) Diacrylate-Nanogels Synthesized by Mini-emulsion Polymerization

被引：0
|
作者：
Radu, Anita Laura [1 ]
Gavrila, Ana Mihaela [1 ]
Cursaru, Bogdan [1 ]
Spatarelu, Catalina Paula [1 ]
Sandu, Teodor [1 ]
Sarbu, Andrei [1 ]
Teodorescu, Mircea [2 ]
Perrin, Francois Xavier [3 ]
Iordache, Tanta Verona [1 ]
Zaharia, Anamaria [1 ]
机构：
[1] Natl Inst Res & Dev Chem & Petrochem ICECHIM, Adv Polymer Mat & Polymer Recycling Grp, 202 Splaiul Independentei, Bucharest 060021, Romania
[2] Univ Politehn Bucuresti, Dept Bioresources & Polymer Sci, 1-7 Polizu, Bucharest 011061, Romania
[3] Univ Sud Toulon Var, MAPIEM Lab, BP 132, F-83957 La Garde, France
来源：
MATERIALE PLASTICE | 2019年 / 56卷 / 03期
关键词：
poly(ethylene glycol) diacrylates macromer; self crosslinking; mini-emulsion; nanogels; MOLECULAR-WEIGHT; DELIVERY; HYDROGELS; RELEASE; NANOPARTICLES; SUSPENSION; PEG;
D O I：
暂无
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
New nanogels (NGs) with tailored properties were obtained using a mini-emulsion technique, from poly(ethylene glycol) diacrylate (PEGDA) self-crosslinking macromers of various molecular weight. By modifying synthesis parameters (hydrophilic-lipophilic balance, emulsifier and the ratio of organic-aqueous medium), optimum recipes of NGs were selected. Therefore, the molecular weight distribution and the functionalization degree of the PEGDA(2000) macromer were assessed by Gel Permeation Chromatography (GPC) and Nuclear Magnetic Resonance (NMR), respectively. Furthermore, the PEGDA-NGs were investigated by Dynamic Light Scattering (DLS) and Transmission Electron Microscopy (TEM) for size distributions and morphology. DLS and TEM results confirm that these new PEGDA-NGs hold potential for biomedical applications.
引用
收藏
页码：514 / 519
页数：6
相关论文
共 50 条
  • [1] MINI-EMULSION FORMATION AND POLYMERIZATION OF STYRENE
    PAN, ZR
    FAN, H
    WENG, ZX
    HUANG, ZM
    POLYMER INTERNATIONAL, 1993, 30 (02) : 259 - 264
  • [2] The inverse mini-emulsion polymerization of acrylamide
    Capek, I
    DESIGNED MONOMERS AND POLYMERS, 2003, 6 (04) : 399 - 409
  • [3] Particle size distribution in mini-emulsion polymerization
    Landfester, K
    Schork, FJ
    Kusuma, VA
    COMPTES RENDUS CHIMIE, 2003, 6 (11-12) : 1337 - 1342
  • [4] Radical polymerization in direct mini-emulsion systems
    Capek, I
    Chern, CS
    NEW POLYMERIZATION TECHNIQUES AND SYNTHETIC METHODOLOGIES, 2001, 155 : 101 - 165
  • [5] Kinetics of mini-emulsion polymerization of vinyl acetate
    Qiao, Jin-Zhong
    Wang, Tong
    Zhan, Mao-Sheng
    Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering, 2009, 25 (11): : 13 - 15
  • [6] Kinetic study of the mini-emulsion polymerization of styrene
    Wang, CC
    Yu, NS
    Chen, CY
    Kuo, JF
    POLYMER, 1996, 37 (12) : 2509 - 2516
  • [7] Composite Nanogels Based on Zeolite-Poly(ethylene glycol) Diacrylate for Controlled Drug Delivery
    Spatarelu, Catalina Paula
    Chiriac, Anita-Laura
    Cursaru, Bogdan
    Iordache, Tanta-Verona
    Gavrila, Ana-Mihaela
    Cojocaru, Crina-Thea
    Botez, Razvan-Edward
    Trica, Bogdan
    Sarbu, Andrei
    Teodorescu, Mircea
    Tofan, Vlad
    Perrin, Francois-Xavier
    Zaharia, Anamaria
    NANOMATERIALS, 2020, 10 (02)
  • [8] Voltage activation of poly (ethylene glycol) diacrylate
    Ghosh, Animesh
    Meyyappan, Priyavadana
    Steele, Terry W. J.
    PROGRESS IN ORGANIC COATINGS, 2022, 165
  • [9] Superparamagnetic nanocomposite particles synthesized using the mini-emulsion technique
    Gyergyek, Saso
    Makovec, Darko
    Mertelj, Alenka
    Huskic, Miroslav
    Drofenik, Mihael
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2010, 366 (1-3) : 113 - 119
  • [10] Micropatterning of Poly(ethylene glycol) Diacrylate Hydrogels
    Ali, Saniya
    Cuchiara, Maude L.
    West, Jennifer L.
    MICROPATTERNING IN CELL BIOLOGY, PT C, 2014, 121 : 105 - +
12345