Magnetic molecular materials with paramagnetic lanthanide ions

被引：83
|
作者：
Wang BingWu [1 ]
Jiang ShangDa [1 ]
Wang XiuTeng [1 ]
Gao Song [1 ]
机构：
[1] Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
来源：
SCIENCE IN CHINA SERIES B-CHEMISTRY | 2009年 / 52卷 / 11期
基金：
中国国家自然科学基金;
关键词：
lanthanide; coordination compound; magnetic coupling; magnetic ordering; magnetic relaxation; single-molecule magnet; single-chain magnet; single-ion magnet; NITRONYL NITROXIDE RADICALS; 4F-3D COORDINATION POLYMERS; LIGAND-FIELD PARAMETERS; F-ELECTRONIC STRUCTURES; SINGLE-CHAIN MAGNETS; SCHIFF-BASE COMPLEX; CRYSTAL-STRUCTURE; GROUND-STATE; DINUCLEAR COMPLEXES; COPPER(II)-GADOLINIUM(III) COMPLEXES;
D O I：
10.1007/s11426-009-0275-9
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The diverse magnetic properties of lanthanide-based magnetic molecular materials are introduced in the following organization. First, the general aspects of magnetic molecular materials and electronic states of lanthanide ions are introduced. Then the structures and magnetic properties are described and analyzed for molecules with one lanthanide ion, 4f-4f, 4f-3d and 4f-p magnetic coupling interactions. In each section, magnetic coupling, magnetic ordering and magnetic relaxation phenomenon are briefly reviewed using some examples. Finally, some possibilities of developing magnetic molecular materials containing lanthanide ions are discussed in the outlook part.
引用
收藏
页码：1739 / 1758
页数：20
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