Novel isothiocyanato esters appended to task-specific ionic liquid as new tools for ionic liquid phase organic synthesis (IoLiPOS)

被引：36
|
作者：
Hakkou, H
Vanden Eynde, JJ
Hamelin, J
Bazureau, JP
机构：
[1] Univ Rennes 1, Inst Chim Synth & Electrosynth Organ 3, UMR 6510, F-35042 Rennes, France
[2] Xavier Univ, Coll Pharm, Dept Basic Pharmaceut Sci, New Orleans, LA 70125 USA
来源：
SYNTHESIS-STUTTGART | 2004年 / 11期
关键词：
task-specific ionic liquid; isothiocyanato ester; ionic liquid phase;
D O I：
10.1055/s-2004-829121
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The synthesis of isothiocyanato esters appended to (polyethylene glycol)-ionic liquid phases is reported. The starting task-specific ionic liquids (TSILs) were functionalized in good yields with bromoacetic acid or 4-chlorobutyroyl chloride by usual esterification reaction conditions. In the second step, the isocyanato esters appended to TSILs were obtained by displacement with potassium thiocyanate in refluxing anhydrous MeCN. The isothiocyanato-TSILs were characterized by NMR (H-1, C-13), mass spectrometry (MS) and IR spectroscopy.
引用
收藏
页码：1793 / 1798
页数：6
相关论文
共 50 条
  • [1] Synthesis of novel polyfluorene-derived task-specific ionic liquid
    Zhang, DJ
    Chen, L
    Chen, JM
    Liang, YM
    Zhou, HD
    SYNTHETIC COMMUNICATIONS, 2005, 35 (20) : 2609 - 2613
  • [2] Liquid-phase synthesis of polyhydroquinoline using task-specific ionic liquid technology
    Legeay, Jean Christophe
    Goujon, Jean Yves
    Eynde, Jean Jacques Vanden
    Toupet, Loic
    Bazureau, Jean Pierre
    JOURNAL OF COMBINATORIAL CHEMISTRY, 2006, 8 (06): : 829 - 833
  • [3] Synthesis and Characterization of Task-specific Schiff-base Ionic Liquid
    Gao Li-Xia
    Yu Jiang
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2013, 34 (01): : 108 - 114
  • [4] Design and synthesis of a task-specific ionic liquid as a transducer in potentiometric sensors
    Ping, Jianfeng
    Wang, Yixian
    Ying, Yibin
    Wu, Jian
    RSC ADVANCES, 2013, 3 (43) : 19782 - 19784
  • [5] Synthesis of carboxymethylpyridine task-specific ionic liquid under ultrasonic irradiation
    Zhang, C. (czhanghxhg@163.com), 1600, Zhejiang University (27):
  • [6] Task-specific ionic liquid for solubilizing metal oxides
    Nockemann, Peter
    Thijs, Ben
    Pittois, Stijn
    Thoen, Jan
    Glorieux, Christ
    Van Hecke, Kristof
    Van Meervelt, Luc
    Kirchner, Barbara
    Binnemans, Koen
    JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (42): : 20978 - 20992
  • [7] Dissolution of metal oxides in task-specific ionic liquid
    Richter, Janine
    Ruck, Michael
    RSC ADVANCES, 2019, 9 (51) : 29699 - 29710
  • [8] Ionic Liquid-Phase Organic Synthesis (IoLiPOS) Methodology Applied to Cross Aldol Reaction
    Hakkou, H.
    Carrie, D.
    Paquin, L.
    Bazureau, J-P.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2011, 47 (03) : 371 - 373
  • [9] A task-specific biodegradable ionic liquid: a novel catalyst for synthesis of bicyclic ortho-aminocarbonitriles
    Gaikwad, D. S.
    Undale, K. A.
    Patil, D. B.
    Patravale, A. A.
    Kamble, A. A.
    JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2018, 15 (05) : 1175 - 1180
  • [10] A task-specific biodegradable ionic liquid: a novel catalyst for synthesis of bicyclic ortho-aminocarbonitriles
    D. S. Gaikwad
    K. A. Undale
    D. B. Patil
    A. A. Patravale
    A. A. Kamble
    Journal of the Iranian Chemical Society, 2018, 15 : 1175 - 1180
12345