The influence of solvation on the electronic structure, emission spectra, and thermodynamic characteristics of formation of exciplexes

被引：0

作者：

Kuz'min, MG ^{[1
]}

Dolotova, EV ^{[1
]}

Soboleva, IV ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Fac Chem, Moscow 119899, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY | 2002年 / 76卷 / 07期

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The nature of the influence of temperature on the electronic structure, emission spectra, and energy characteristics of formation of exciplexes is considered. It is shown that the model of mutually consistent polarizations of the medium and exciplex suggested earlier and based on a simple continual approach to the solvation of exciplex. dipoles by a dielectric medium can be used to quantitatively take into account the role played by the enthalpy and entropy of solvation in the formation of emission spectra of exciplexes and in the thermodynamics of their formation.

引用

页码：1109 / 1118

页数：10

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