Copolymerization of tetrafluoroethylene and ethylene in fluorinated organic solvents

被引：1
|
作者：
Miyake, H [1 ]
Yamabe, M [1 ]
机构：
[1] Asahi Glass Co Ltd, Res Ctr, Kanagawa Ku, Yokohama, Kanagawa 2218755, Japan
来源：
EUROPEAN POLYMER JOURNAL | 2000年 / 36卷 / 02期
关键词：
Fluorinated organic solvent - Trichlorofluoromethane solvent - Trichlorotrifluoroethane solvent - Unimolecular termination;
D O I：
10.1016/S0014-3057(99)00072-5
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Copolymerization of tetrafluoroethylene and ethylene was investigated in trichlorotrifluoroethane and trichlorofluoromethane solvents. The high solubility of the monomers in these solvents made polymerization under reduced pressures possible. Trichlorofluoromethane acted as an effective chain transfer agent to regulate the molecular weight. Kinetic studies showed that bimolecular and unimolecular termination prevailed at low and high polymer concentrations, respectively. (C) 1999 Elsevier Science Ltd. All rights reserved.
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页码：379 / 384
页数：6
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