3D nickel(II) and cobalt(II) complexes based on 1,4-bis(1,2,4-triazol-1-yl) butane (btb) and PF6- synthons

被引：2
|
作者：
Wang, Kai [1 ]
Qi, Xiao-Yu [1 ]
Wang, Qing-Lun [1 ]
Ren, Hong-Xia [2 ]
Ma, Yue [1 ]
Cheng, Peng [1 ]
Liao, Dai-Zheng [1 ]
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
[2] Nankai Univ, Minist Educ, Key Lab Adv Energy Mat Chem, Tianjin 300071, Peoples R China
来源：
INORGANICA CHIMICA ACTA | 2016年 / 441卷
基金：
中国国家自然科学基金;
关键词：
Coordination polymer; Bis(triazole) ligands; Crystal structure; Magnetic properties; METAL-ORGANIC FRAMEWORKS; MANGANESE COORDINATION POLYMERS; FLEXIBLE BIS(TRIAZOLE); CRYSTAL-STRUCTURES; MAGNETIC-PROPERTIES; ANION-EXCHANGE; LIGAND; SERIES; LUMINESCENT; COPPER(II);
D O I：
10.1016/j.ica.2015.11.014
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The diffusion reaction of 1,4-bis(1,2,4-triazol-1-yl) butane (btb) with Co(II)/Ni(II) ions as well as counter anions (PF6) yielded two new coordination polymers, [Co-1.5(btb)(4.5)](PF6)(3) (1) and [Ni-2(btb)(6)](PF6)(4) (2). Both complexes have 3D uninodal 6-connected (4(12),6(3)) net topology, forming triple interpenetrating structure. The distance between adjacent metal ions via btb bridging ligand is in the range of 13.930-14.181 angstrom and 13.982-14.086 angstrom, respectively. The magnetic behaviors of complexes 1 and 2 have been analyzed by one-ion approximation with spin-orbit coupling and zero-field splitting, respectively. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：131 / 136
页数：6
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