Water-soluble polymers with tunable temperature sensitivity: Solution behavior

被引：40

作者：

Rackaitis, M ^{[1
]}

Strawhecker, K ^{[1
]}

Manias, E ^{[1
]}

机构：

[1] Penn State Univ, Dept Mat Sci & Engn, University Pk, PA 16802 USA

来源：

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS | 2002年 / 40卷 / 19期

关键词：

water-soluble polymers; stimuli-sensitive polymers; phase behavior; polyesters; polyamides;

D O I：

10.1002/polb.10284

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A series of linear polymers with a systematically varied hydrophobic/hydrophilic balance in their monomer was synthesized and explored its water-solution behavior. It was shown through simple scaling arguments that these temperature-responsive polymers obey a linear dependence of the transition temperature on the monomeric hydrophobic/hydrophilic balance. By tailoring the monomer stoichiometry, transition temperatures from 7 to 70°C in water at ambient pressures were achieved.

引用

页码：2339 / 2342

页数：4

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