A facile indium-mediated synthesis of protected and unprotected [1-(hydroxymethyl)vinyl]alkanols

被引:0
|
作者
Moirangthem, Nimalini D. [1 ]
Thingom, Bhavana [1 ]
Laitonjam, Warjeet S. [1 ]
机构
[1] Manipur Univ, Dept Chem, Imphal 795003, Manipur, India
来源
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY | 2009年 / 48卷 / 03期
关键词
Indium-mediated; protected; unprotected; vinylalkanols; METHYLENE-GAMMA-BUTYROLACTONES; ACTIVATED DOUBLE-BONDS; AQUEOUS-MEDIA; ALDEHYDES; ACID;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Protected and unprotected [1-(hydroxymethl)vinyl]alkanols (7 and 8) have been synthesized from the homogented gamma-hydroxy esters 4 which have been prepared by indium-mediated allylation of the rearranged bromides 3 derived from hydroxyl esters 2 in water medium.
引用
收藏
页码:455 / 459
页数:5
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