Highly Efficient lsobutyraldehyde-Mediated Epoxidation of Cyclic Alkenes with Dioxygen Catalyzed by a Novel Dimeric Manganese(II) Complex Containing an Easy-to-Prepare Flexible Carboxamide Ligand

被引：23

作者：

Khavasi, Hamid Reza ^{[1
]}

Sasan, Koroush ^{[1
]}

Pirouzmand, Mahtab ^{[1
]}

Ebrahimi, Samad Nejad ^{[2
]}

机构：

[1] Shahid Beheshti Univ, GC, Dept Chem, Tehran 1983963113, Iran

[2] Shahid Beheshti Univ, GC, Dept Phytochem, Med Plants & Drug Res Inst, Tehran 1983963113, Iran

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 13期

关键词：

MOLECULAR-OXYGEN; OLEFINS; OXIDATIONS; ALDEHYDES;

D O I：

10.1021/ic900334w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dioxygen epoxidation of cyclic alkenes into their corresponding epoxides was successfully achieved in good yield by using a novel binuclear manganese carboxamide complex as the catalyst and isobutyraldehyde as the cosubstrate.

引用

页码：5593 / 5595

页数：3

共 5 条

[1] Novel manganese complex as an efficient catalyst for the isobutyraldehyde-mediated epoxidation of cyclic alkenes with dioxygen
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