One-Pot Protocol for Synthesis of -Organosulfonyloxy Ketones from Secondary Alcohols Using Hypervalent Iodine(V)-Mediated Oxidations

被引：1
|
作者：
Deshmukh, Swapnil S. [1 ]
Huddar, Sameerana N. [1 ]
Akamanchi, Krishnacharya G. [1 ]
机构：
[1] Inst Chem Technol, Dept Pharmaceut Sci & Technol, Bombay 400019, Maharashtra, India
来源：
SYNTHETIC COMMUNICATIONS | 2009年 / 39卷 / 17期
关键词：
Alcohols; Dess-Martin periodinane; hypervalent iodine(V) reagents; organosulfonic acids; -organosulfonyloxy ketones; solvent-free reaction condition; ALPHA-TOSYLOXYLATION; IODINE; <HYDROXY(TOSYLOXY)IODO>BENZENE; CHEMISTRY; REAGENTS;
D O I：
10.1080/00397910902730952
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
-Tosyloxy ketones and -mesyloxy ketones were directly prepared from alcohols in one pot by treatment with hypervalent iodine(V) reagents in combination with p-toluenesulfonic acid and methanesulfonic acid, respectively, in moderate to good yields. Reactions were also feasible under solvent-free conditions.
引用
收藏
页码：3101 / 3110
页数：10
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