Photolysis of matrix-isolated CF3C(O)SH and CF3C(O)SCl

被引：6
|
作者：
Ulic, SE
Gobbato, KI
DellaVedova, CO
机构：
[1] NATL UNIV LA PLATA,CEQUINOR,CONICET,RA-1900 LA PLATA,ARGENTINA
[2] UNIV NACL LUJAN,DEPT CIENCIAS BASICAS,LUJAN,ARGENTINA
[3] NATL UNIV LA PLATA,LAB SERV IND & SISTEMA CIENT,DEPT QUIM,CIC,CONICET,RA-1900 LA PLATA,ARGENTINA
来源：
JOURNAL OF MOLECULAR STRUCTURE | 1997年 / 407卷 / 2-3期
关键词：
photolysis; matrix-isolated species; FTIR;
D O I：
10.1016/S0022-2860(96)09639-1
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Perfluoroacetylthiol, CF3C(O)SH, and perfluoroacetylsulphenyl chloride, CF3C(O)SCl, were irradiated in an inert gas matrix to produce CF3SH and CO, and CF3SCl, CF3Cl, CO and SCO, respectively. The compounds are identified by evaluating the apparition of new bands in the FTIR spectrum of the matrix-isolated substance. The results are compared with related studies of similar compounds taking into account both the irradiation and the stability of the formed products. (C) 1997 Elsevier Science B.V.
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页码：171 / 175
页数：5
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