Functional polymers from novel carboxyl-terminated trithiocarbonates as highly efficient RAFT agents

被引：1422
|
作者：
Lai, JT [1 ]
Filla, D [1 ]
Shea, R [1 ]
机构：
[1] Noveon Inc, Brecksville, OH 44141 USA
来源：
MACROMOLECULES | 2002年 / 35卷 / 18期
关键词：
D O I：
10.1021/ma020362m
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
An overview is given on an easy synthesis of carbonxyl-terminated trithiocarbonates. Telechelic carboxyl-terminated polymers are shown to be easily obtained when dicarboxyl trithocarbonate is employed. Bulk or solution polymerizations of alkyl acrylates, acrylic acid, and styrene are well-controlled. Some disproportionation at chain ends are observed with methyl methacrylate.
引用
收藏
页码：6754 / 6756
页数：3
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