HIPE Polymerization Materials Functionalized with Iodic-BODIPY on the Surface as Porous Heterogeneous Visible-Light Photocatalysts

被引：10
|
作者：
Li, Wenliang [1 ,4 ,5 ]
Li, Leijiao [3 ]
Cui, Guihua [1 ]
Bai, Yu [1 ]
Xiao, Xiao [1 ]
Li, Yuxin [4 ]
Yan, Lesan [2 ]
机构：
[1] Jilin Med Univ, Jilin Rd 5, Jilin 132013, Peoples R China
[2] Univ Penn, Dept Bioengn, 210 S 33rd St, Philadelphia, PA 19104 USA
[3] Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Renmin St 5625, Changchun 130022, Peoples R China
[4] Northeast Normal Univ, Sch Life Sci, Jingyue St 2555, Changchun 130024, Peoples R China
[5] Jilin Normal Univ, Minist Educ, Key Lab Preparat & Applicat Environm Friendly Mat, Zhuoyue St 399, Changchun 130103, Peoples R China
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2017年 / 12卷 / 04期
基金：
中国国家自然科学基金;
关键词：
BODIPY; heterogeneous materials; photocatalysis; polymerization; sulfide oxidation; POLYHIPE POLYMERS; OXIDATION; 2,4,6-TRIPHENYLPYRYLIUM; CHEMISTRY; SULFIDES; ZEOLITE; SILICA; DYES;
D O I：
10.1002/asia.201601628
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A high internal phase emulsion polymerization (PolyHIPE) material, with iodine-functionalized boron-dipyrromethene (iodic-BODIPY) immobilized on its surface, composes a porous heterogeneous organic photocatalyst (iodic-BODIPY-PolyHIPE). It shows high catalytic efficiency on the selective oxidation reaction of aromatic sulfides under visible light. The substrates were almost fully converted to their corresponding sulfoxides and no sulfones were observed. Most importantly, iodic-BODIPY-PolyHIPE shows > 1.6-fold reaction rate compared to the previous non-inorganic heterogeneous photocatalysts.
引用
收藏
页码：392 / 396
页数：5
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