Reaction of acetyl and benzoyl chlorides with pyridines and pyridine N-oxides

被引：3
|
作者：
Rybachenko, VI
Schroeder, G
Chotii, KY
Lenska, B
Red'ko, AN
机构：
[1] Natl Acad Sci Ukraine, Litvinenko Inst Phys Organ & Coal Chem, UA-83114 Donetsk, Ukraine
[2] Adam Mickiewicz Univ, Fac Chem, PL-61712 Poznan, Poland
来源：
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2004年 / 40卷 / 03期
关键词：
D O I：
10.1023/B:RUJO.0000034981.44740.a5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The rate of formation of N- and O-acetyl and benzoyl salts of pyridines and pyridine N-oxides in acetonitrile and methylene chloride and equilibria therein were studied. The process occurs in one step following the S(N)2 mechanism with a small degree of bond rupture in the transition state.
引用
收藏
页码：412 / 416
页数：5
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