Chemical tuning of the magnetic properties of epitaxial BaFe12-x,ScxO19 (0≤x≤2.1) hexaferrite thin films

The composition dependent magnetic structure in epitaxial BaFe12-x,ScxO19 (0 <= x <= 2.1, BaScM) thin films have been investigated. Results show that with increasing Sc3+ content, the out-of-plane c-axis lattice constants of BaScM films increase but do not follow the Vegard's law. The changes in hysteresis loops indicate a variation of magneto-crystalline anisotropy from the uniaxial-type for BaFe12O19 to the near-planar type for BaFe10.2Sc1.8O1.9. The remanent magnetic domains change from a mixture of dots and maze-like structure to more maze-like structure as the Sc(3+ )content increases. The above magnetic results can be explained by a composition dependent magnetic structure transition from collinear-type ferrimagnetic magnetic structure to the non-collinear conical magnetic structure which appears at Sc3+ content x >= 0.6. The ZFC/FC curves further show that the conical magnetic structure transition temperature (T-cone) of the films increases with the Sc3+ content until x >= 2.1. The above results may help better apply BaScM films in the electromagnetic devices. (C) 2019 Elsevier B.V. All rights reserved.