Synthesis, Crystal Structure and Electrochemical Property of the Complex [Cu(m-NBA)(2,2′-bipy)(H2O)2]•m-NBA•H2O

被引：0

作者：

Chen Zhi-Min ^{[1
]}

Zhang Fu-Xing ^{[1
]}

Zeng Rong-Ying ^{[1
]}

Kuang Dai-Zhi ^{[1
]}

Feng Yong-Lan ^{[1
]}

Wang Jian-Qiu ^{[1
]}

机构：

[1] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 25卷 / 03期

关键词：

m-nitrobenzoic acid; 2,2 '-bipyridine; copper(II) complex; crystal structure; HYDROTHERMAL SYNTHESIS;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex [Cu(m-NBA)(2,2'-bipy)(H2O)(2)]center dot m-NBA center dot H2O was obtained by self-assembly of m-nitrobenzoic acid. 2,2'-bipyridine and copper(II). The crystal structure of the complex has been determined by X-ray diffraction single crystal Structure analysis. The crystal belongs to monoclinic system, space group P2(1)/n. The cell parameters are: a=0.705 65(9) nm, b=2.901 2(4) nm, c=1.271 52(2) nm; beta=92.895(2)degrees, and V=2.599 8(6) nm(3), D-c= 1.551 g.cm(-3), Z=4, mu(Mo K alpha)=9.09 cm(-1), F(000)=1 244, R-1=0.0407, omega R-2=0.085 5[I>2 sigma(I)]. The crystal structure shows that the copper M ion is coordinated with two nitrogen atoms from one 2,2'-bipyridine Molecule, one oxygen atom from one m-nitrobenzoic acid Molecule and and two oxygen atoms from two water molecules, forming a distorted coordination square-pyramid. The cyclic voltametric behavior of the complex was also studied. CCDC: 687131.

引用

页码：548 / 551

页数：4

共 13 条

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