Kinetics, mechanism and thermodynamic studies of rhodium(III) catalysed oxidation of alanine by alkaline hexacyanoferrate(III)

被引：0
|
作者：
Chourasia, P. K. [1 ]
Bhattacharjee, N. C. [1 ]
Singh, T. K. [1 ]
机构：
[1] Magadh Univ, Dept Chem, Bodh Gaya 824234, Bihar, India
来源：
JOURNAL OF THE INDIAN CHEMICAL SOCIETY | 2009年 / 86卷 / 04期
关键词：
Rhodium(III); mechanism; hexacyanoferrate(III); alanine; ACID;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The kinetics and mechanism of rhodium(III) catalysed oxidation of alanine in alkaline solution of hexacyanoferrate(III) have been studied. The kinetic data shows zero order dependence on each hexacyanoferrate(III) and sodium hydroxide whereas first order dependence each on alanine and Rh(III). Negligible effect of ionic strength of the medium has been reported. A suitable mechanism consistant with the observed kinetics has been suggested.
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页码：364 / 366
页数：3
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