Preparation of bromoiodopropenoic acids by stereospecific nucleophilic substitution at vinylic carbon

被引：0
|
作者：
Lough, Alan
McKague, A. Bruce [1 ]
机构：
[1] CanSyn Chem Corp, 200 Coll St, Toronto, ON M5S 3E5, Canada
[2] Univ Toronto, Dept Chem, Toronto, ON M5S 1A1, Canada
来源：
SYNTHETIC COMMUNICATIONS | 2006年 / 36卷 / 22期
关键词：
bromoiodopropenoic acids; stereospecific substitution; vinylic carbon;
D O I：
10.1080/00397910600941430
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The bromoiodopropenoic acids (E)-2-bromo-3-iodopropenoic acid 5 and (Z)-2-bromo-3-iodopropenoic acid 6 were prepared by stereospecific nucleophilic substitution of the corresponding vinylic bromides. The structure of the (Z)-isomer was confirmed by X-ray crystallography.
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页码：3387 / 3391
页数：5
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