The application of chiral ferrocene ligands in palladium-catalyzed asymmetric reactions

被引：0
|
作者：
Liu Zhende [1 ]
He Xuchang [1 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Biol Sci, Shanghai Inst Meteria Med, Shanghai 201203, Peoples R China
来源：
PROGRESS IN CHEMISTRY | 2006年 / 18卷 / 11期
关键词：
chiral ferrocene ligands; palladium-catalyzed reaction; asymmetric allylic substitution;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This article briefly describes recent progress on palladium-catalyzed asymmetric allylic substitution reactions using chiral ferrocene ligands, including allylic alkylation, allylic amination and allylic sulfonylation. The Claisen rearrangement, Diels-Alder reaction, Heck reaction, asymmetric carbonylation, asymmetric hydrosilylation and C-C bond cleavage using chiral ferrocene ligands as catalyst are also reviewed. Some reaction mechanisms and perspective are discussed.
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页码：1489 / 1497
页数：9
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