Thermal and gas permeation properties of copolymers derived from 3-methacryloxypropyltris(trimethylsiloxy) silane and adamantyl group-containing methacrylate derivatives

被引：0

作者：

Ando, Shota ^{[1
]}

Yoshida, Akihiro ^{[1
]}

Nakagawa, Masao ^{[1
]}

Nagai, Kazukiyo ^{[1
]}

机构：

[1] Meiji Univ, Dept Appl Chem, Tama Ku, Kawasaki, Kanagawa 2148571, Japan

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2016年 / 133卷 / 11期

关键词：

copolymers; functionalization of polymers; membranes; radical polymerization; separation techniques; TRANSPORT PROPERTIES; SEPARATION PROPERTIES; AROMATIC POLYAMIDES; AIR SEPARATION; MEMBRANES; ACID); PERMEABILITIES; PERFORMANCE; POLYIMIDES; POLYMERS;

D O I：

10.1002/APP.43129

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Novel copolymer membranes derived from three types of adamantyl group-containing methacrylate derivatives and 3methacryloxypropyltris(trimethylsiloxy) silane (SiMA) were synthesized via free radical polymerization. The thermal and permeation properties of these copolymer membranes were investigated. Copolymer membranes with less than 11.9 mol % adamantane content exhibited good membrane forming abilities that are suitable for permeation measurement. The decomposition temperature of all copolymers increased up to approximately 40-80 degrees C with increasing adamantane content compared with poly( SiMA). Moreover, the glass transition temperature ( T-g) of all copolymers increased up to approximately 46-60 degrees C with increasing adamantane content compared with the theoretical value, which was estimated from Fox equation. 1-Adamantyl methacrylate copolymer had the highest fractional free volume among the three types of adamantly group-containing methacrylate derivatives. The gas permeability coefficient of this copolymer increased by 22-45% with increasing adamantane content compared with that of poly( SiMA). (c) 2015 Wiley Periodicals, Inc.

引用

页数：12